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How can entropy increase in a reversible process?

Physics Asked on August 12, 2021

According to Wikipedia, a reversible process is “a process whose direction can be “reversed” by inducing infinitesimal changes to some property of the system via its surroundings, with no increase in entropy.”

However, for isothermal processes, any reversible heat added to the system at constant temperature increases entropy. So, a reversible process of heating is causing a change in entropy. This seems to contradict the definition above.

Where have I gone wrong?

2 Answers

The entropy does not change if the process is reversible and the system is closed. In your example you are taking into account only the subsystem which indeed has its entropy increased. If you consider also the neighbourhood then you see that its entropy change is negative (loosing heat) and that precisely cancels the entropy change of the subsystem. The entropy of the whole closed system does not change.

Answered by Diracology on August 12, 2021

When one says that entropy does not increase for a reversible process, the entropy they are talking about is the total entropy of an isolated system. If we consider the universe as our isolated system total entropy is equal to the entropy of system + the entropy of the surroundings.

So, for a reversible process where heat is added into the system, the entropy of the system does increase however the entropy of the surroundings in any reversible process = -(entropy of the system)and ultimately, the total entropy is zero.

Answered by Aditya Bharadwaj on August 12, 2021

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