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Why do we say that at boiling point liquid and vapour exist in equilibrium?

Physics Asked on June 22, 2021

I understand that at boiling point, vapour pressure becomes equal to the external pressure. But in my textbook it is written that at boiling point liquid and vapour exist in equilibrium. What does it mean by ‘vapour and liquid exist in equilibrium’ and also why do they exist in equilibrium?

One Answer

In a closed container at a fixed temperature, the rate at which molecules leave the liquid is equal to the rate at which they return. Boiling in a liquid occurs when the temperature at the bottom allows bubbles to form and grow. The vapor pressure in the bubble must equal that of the surrounding liquid. The bubbles are almost like closed containers.

Answered by R.W. Bird on June 22, 2021

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